Early solar system aqueous activity: K isotope evidence from Allende

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.     

BDS卫星钟差半参数平差模型异常数据探测与处理

针对北斗卫星钟差数据中出现钟跳、粗差等异常数据频次较高的问题,将半参数平差模型引入BDS的钟差数据的处理过程中。首先,在考虑系统误差的同时,改进了常用的钟差模型;其次,综合考虑异常数据和系统误差,利用补偿最小二乘原理和极值求解方法,详细推导了分离异常数据前后参数和非参数估计值与相应观测值改正数的关系表达式,实现了异常数据的定值、参数求解和系统误差分离。在此基础上,引入Cook距离,给出了利用参数分量和非参数分量的Cook距离及混合Cook距离,去判断异常值的位置,并给出了一些参数的选取方法及相应的处理措施,实现了卫星钟差异常数据的定位和定值以及部分系统误差的分离。最后,采用武汉大学GNSS中心提供的采样间隔为5 min的北斗卫星精密钟差数据,将本文方法与常用方法进行了试验对比。试验结果表明,本文方法能够有效地识别并处理卫星钟差数据中的异常值,有效克服了基于经验阈值钟差异常数据探测方法的不足,且该方法对于量级较小的异常钟差数据也有很好的探测效果,一定程度丰富了现有的BDS钟差数据质量控制方法。     

基于时相变化的晴空条件下Himawari-8 AHI火点检测

Himawari-8静止气象卫星具有高空间分辨率、高观测频次和高时效特点,对于火点检测具有很强优势。对Himawari-8卫星的3.9μm和11.2μm两通道亮温进行了连续时相变化研究,得出两通道的亮温在时间上的变化差值稳定且规律明显。根据两通道的亮温时相特征,考虑白天可见光对3.9μm通道的影响,并结合火点产生时引起的亮温变化特征,提出了适用于晴空条件下改进的火点检测算法。在多处进行了此算法的实验,例如2018-11-27 T 16:40(UTC时)河北张家口市桥东区一化工厂附近发生的严重爆炸起火事件以及2019-02-28澳大利亚西南部发生的火灾事件,均快速有效的检测到了火点。实验表明,改进的火点检测算法能很好的进行火点检测,并能解决晨昏交界、冰雪下垫面、常规火源点、太阳耀光等火点检测的难题。     

Tracing the settlement region of massive floating green algae in the Yellow Sea

Outbreaks of large-scale green tides formed by Ulva prolifera in the Yellow Sea(YS)cause heavy ecological damages and huge economic losses.However,the ecological consequences of green tides remain poorly understood due to the lack of knowledge on the settlement region of massive green algae floating in the YS.In this study,we established a method to trace the settlement region of floating green algae,using 28-isofucosterol preserved in sediment as the specific biomarker for green algae.Sterols including 28-isofucosterol in surface sediment samples collected during an investigation in the YS and the Bohai Sea(BS)in August 2015 were analyzed using gas chromatography coupled with a mass spectrometer(GC-MS).Based on the content of 28-isofucosterol in sediment samples,the potential settlement region of loating green algae was identified in the sea area southeast to the Shandong Peninsula around the sampling site H06(122.66°E,36.00°N).This paper presents a first result on the settlement region of floating green algae in the YS for providing a solid basis to elucidate the ecological consequences of green tides in the area.     

重力数据约束的二维地震层析成像在台湾海峡南部的应用

地震-重力联合反演可以降低多解性，针对大勘探范围内岩石波速-密度关系存在较大散布的问题，引入交叉梯度结构约束构建统一的目标函数是一种有效的解决方案。利用台湾海峡南部HX-13测线进行验证：由于火成岩侵入体的存在，部分区域难以拾取可靠的地震初至，常规的走时反演无法准确恢复基底面的形态。搜集研究区的船测重力资料，根据地震地质条件和数据特点设置合适的反演参数，实现基于物性和结构双重约束的重力-地震联合反演。由对反演结果的分析和解释可以看出，该方法可在很大程度上弥补地震数据不完备的缺陷，使反演过程稳定，并提高模型的可靠性。     

海南岛海岸带土地利用强度与生态承载力分析

随着海南省进一步开放发展，海岸带区域的土地利用强度逐渐加强，生态保护需求日益增强。利用4期（1990、2000、2009、2015年）海岸带土地利用分类数据，研究海岸带土地开发利用强度，并分析了其生态承载力。结果表明：①耕地和林地是海南岛海岸带地区的主要土地类型。②25年间，海南岛海岸带土地利用强度整体较高且逐年上升，2000—2009年土地利用强度增速最高，达2.03%；海口市和澄迈县土地利用强度4期均值最大，分别为300.5和286.1。③25年来海南岛海岸带生态状况呈下降趋势，57%的海岸带市县实际生态承载压力增长了1倍以上。     

敞开酸溶和偏硼酸锂碱熔ICP-MS法测定多金属矿中的稀土元素及铌钽锆铪

用电感耦合等离子体质谱法(ICP-MS)测定地质样品中的稀土及难熔元素,混合酸敞开酸溶法和碱熔融法是两种主要的溶样方法。但地质样品组分复杂,元素之间存在相互共生的现象,对于特殊元素、特殊样品用传统酸溶法会造成部分元素消解不完全,使测定结果不准确;而碱熔法的操作过程繁琐,且溶液盐度高,易产生基体干扰和堵塞仪器进样系统。本文改进了传统四酸和五酸体系,采用氢氟酸-硝酸-硫酸敞开酸溶体系,用国家一级标准物质制作标准曲线测定15种稀土元素,方法准确度(ΔlgC)为0.001～0.027。同时改进了偏硼酸锂碱熔法,样品用偏硼酸锂碱熔提取,加入氢氧化钠调节溶液至碱性条件,所测元素与偏硼酸锂共沉淀后过滤分离熔剂,再用硝酸复溶测定15种稀土元素及铌钽锆铪。两种溶样方法的测定值与认定值的相对误差为1.09%～9.30%。将混合酸敞开酸溶法测定稀土元素、偏硼酸锂碱熔法测定铌钽锆铪的结果与其他实验室密闭酸溶法相比,两组数据的相对偏差为0.13%～15.32%。本实验表明,混合酸敞开酸溶法适用于测定地质样品中的稀土元素,偏硼酸锂碱熔法不仅适用于测定地质样品中的稀土元素及铌钽锆铪,也适用于测定如古老高压变质岩石及铝含量高的样品中的铌钽锆铪。     

大兴安岭中南段构造岩浆岩带深部地质成矿作用

大兴安岭中南段位于索伦—西拉木伦断裂带与嫩江—白城断裂带交汇域，区内大规模岩浆活动、成矿作用与深部地质活动密切相关。深部地球物理研究成果显示：该区域上地幔存在埋藏较浅的低速、低阻、高热异常体，推断应是深部软流体局部上涌的显示；下地壳存在低密度、低速、高导层，推断是因软流体上涌，诱发下地壳重熔，形成所谓下地壳热流体引起。总之该区域软流层厚度大，热活动性强是引起大规模的岩浆活动及多金属矿床集中分布的深部地质因素。而古生代古亚洲洋洋壳俯冲消减，华北板块、西伯利亚板块陆—陆碰撞拼接及至中生代晚期太平洋板块俯冲作用是引起软流层上涌、下地壳重熔等强烈的壳幔相互作用之源动力。     

自然海岸资源价值核算方法研究与应用

文章通过构建自然海岸资源价值核算指标体系,确定了评估因子量化标准,建立了自然海岸基本价值核算系数计算模型、服务价值核算系数计算模型、综合核算系数计算模型和基准价值计算模型。在此基础上,构建了自然海岸资源价值核算模型,并应用其模型对大连市大陆自然海岸资源价值进行核算。最终得出大连市大陆自然海岸资源总价值约为2 409亿元。     

高分三号SAR影像双阈值变化检测

双阈值合成孔径雷达SAR(Synthetic Aperture Radar)变化检测算法具有在发现变化区域的同时还能确定地表发生后向散射变化类型的优点。针对广义高斯双阈值最小误差法D-GKIT(Dual Generalized Kittler and Illingworth Thresholding)在进行阈值选取时直方图中不同类别像素灰度级重叠严重时,分割结果容易在尖峰单侧选取出双阈值而导致无法正确分割差异图的问题,本文提出一种结合归一化最大类间方差和广义高斯最小误差法GKIT(Generalized Kittler and Illingworth Thresholding)的双阈值SAR变化检测方法。首先,提出以归一化最大类间方差值作为灰度级重叠程度的判别参数,确定阈值的选取顺序及两个候选区间;然后,利用GKIT在候选区间内进行分割,获取单侧阈值及非变化类拟合函数;最后,提出利用非变化类拟合函数更新后的直方图作为另一侧阈值选取基础进行分割,得到对应分割阈值。以宁波地区高分三号(GF-3)SAR卫星影像作为试验研究数据,结果表明:本文方法能较好地解决灰度级重叠时D-GKIT无法进行正确分割的问题,具有良好的变化检测效果和更强的鲁棒性且达到了利用研究区数据验证利用GF-3号SAR卫星影像进行变化检测研究可行性的目的。